catalyst A substance that alters the rate of a chemical reaction, but is itself unchanged at the end of the reaction. Catalysts are specific for particular reactions. In a reversible reaction, the forward and back reactions are catalyzed equally, and the equilibrium position is not altered. Catalysis is either homogenous (the catalysts and reactants being in the same phase, usually gas or liquid), in which case the catalyst usually forms a reactive intermediate which then breaks down; or heterogeneous, in which adsorption of the reactants occurs on the catalytic surface. heterogeneous catalysis is often blocked by impurities called poisons. Catalysts are widely used in industry, as in the contact process, the hydrogenation of oils, and the cracking of large hydrocarbons. Biological catalysts are known as enzymes. Related category PHYSICAL CHEMISTRY Also on this site: Encyclopedia of Alternative Energy & Sustainable Living Encyclopedia of History Transport Concepts & Designs (partner site) |