A

David

Darling

oxidation number

The oxidation number is a number that indicates the degree of ionization. Thus, in the compound sodium oxide, Na2O, sodium (Na+) has an oxidation number of +1, and oxygen (O2–) an oxidation number of –2. In covalent and coordination (complex) compounds, the oxidation number is the electric charge that the atoms would have had if the compound was ionic; for example, in the ion (CuCl4)2-, regarded as formed from Cu2+ and 4Cl, copper has an oxidation number of +2. Oxidation numbers are often used in the names of chemical compounds, as in iron(II) chloride (FeCl2) and iron(III) chloride (FeCl3), formerly called ferrous and ferric chloride.